Core Reactions: Redox
Slide 17 of 42
Distinction between charge and oxidation state
So, in most ionic compounds, often oxidation state of the atom is the same as charge, but not always. In covalent compounds the oxidation state is determined by assigning the shared electrons to the more electronegative element in the molecule.
Because of this there is a difference between charge and oxidation state.
Whereas a charge on a chemical species has a physical basis (difference in state of electrons and protons) oxidation state does not necessarily always have one.