M4 The Periodic Table: Halogens
Slide 34 of 45
Halogen Trends in Reactivity
Going     down Group 7
–Bigger atoms
•one extra full shell of electrons for each period you go down
–Less Reactive
•Harder to gain last electron needed as nucleus is farther away from the valence shell
•In other words when the following reaction take place
–Cl2 (aq) + 2Y-(aq) ฎ 2Cl-(aq) + Y2 (aq)  Where Y- = Br- or I-
•Chlorine is able to gain the electrons from bromide and iodide ion more readily because they don’t hold the electrons as strongly as if chlorine were holding it in its valence shell.
•In other words
–Br2 (aq) + Cl-(aq) ฎ No reaction
•Because chlorine is able to hold the electron more strongly than bromine would hold it.