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M4 Periodic Table I: Periodic Table
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Learning Objectives
  • Pre-requisite: Be able to recall the symbol, position (atomic number), electronic structure and electronic configuration for the first 20 elements in the periodic table.
  • Concepts:
    • Symbol, formula, Element, group, period, atomic number, relative atomic mass
    • Alkali metal, alkaline earth metal, halogen, transition metal
    • Electronic configuration, electronic structure, shell, outer (valence) shell, valence electrons,
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Learning Objectives
  • Skills:
    • Be able to describe the difference between a symbol and a formula for an element
    • Be able to identify the diatomic molecular elements in the periodic table
    • Be able to identify the elements that exist in the liquid and gaseous state
    • Describe the relationship between group number, number of valence electrons and metallic/non-metallic character
    • Describe the relationship between period number and number of shells in the atom of an element


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Why is the Periodic Table important?
  • The periodic table is the most useful tool to a chemist.
  • It organizes an incredible amount of information about all the known elements…in just a small table.


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Pre-Periodic Table Chemistry …
  • …was a mess!!!
  • As therefore no organization of elements, information was difficult to come by.
  • Chemistry didn’t make sense.
  • It was like going shopping to a store that had no organization to speak of.
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Dmitri Mendeleev: Father of the Table
  • HOW HIS WORKED…
  • Put elements in rows by increasing atomic weight.
  • Put elements in columns by the way they reacted.



  • SOME PROBLEMS…
  • He left blank spaces for what he said were undiscovered elements.  (Turned out he was right!)
  • He broke the pattern of increasing atomic weight to keep similar reacting elements together.
  • Some different elements have the same mass e.g.
  • Cobalt and Nickel
  • Polonium & Astatine
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The Current Periodic Table
  • Mendeleev wasn’t too far off.
  • Now the elements are put in rows by increasing ATOMIC NUMBER!!
  • The elements are listed in the periodic table from:
  • left to right  across in increasing atomic (proton) number.
  • There are approximately 115 elements
  • Everything in the Universe is made of 1 or more elements.
  • The horizontal rows are called periods and are labeled from 1 to 7.
  • The vertical columns are called groups are labeled from 1 to 8.
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Periodic table
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Groups…Here’s Where the Periodic Table Gets Useful!!
  • Elements in the same group have similar chemical and physical properties!!
  • (Mendeleev did that on purpose.)
  • Not only that, there is a pattern to their properties.


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Families on the Periodic Table
  • Columns are also grouped into families.
  • Families may be one column, or several columns put together.
  • Families have names rather than numbers.
  • (Just like your family has a common last name.)
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The Periodic Table
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The Periodic Table
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The Periodic Table
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The Periodic Table
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Hydrogen
  • Hydrogen belongs to a family of its own.
  • Hydrogen is a diatomic, reactive gas.
  • Hydrogen was involved in the explosion of the Hindenberg.
  • Hydrogen is promising as an alternative fuel source for automobiles.
  • It is used as rocket fuel.
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Alkali Metals
  • 1st column on the periodic table (Group 1) not including hydrogen.
  • Very reactive metals, always combined with something else in nature (like in salt).
  • Soft enough to cut with a butter knife.
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Alkaline Earth Metals
  • Second column on the periodic table. (Group 2)
  • Reactive metals that are always combined with nonmetals in nature.
  • Several of these elements are important mineral nutrients (such as Mg and Ca).
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Transition Metals
  • Elements in the middles of the periodic table.
  • Less reactive, harder metals.
  • Includes metals used in jewelry and construction.
  • Metals used “as metal.”
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Boron Family
  • Elements in group 3
  • Aluminum metal was once rare and expensive, not a “disposable metal.”



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Carbon Family
  • Elements in group 4
  • Contains elements important to life and computers.
  • Carbon is the basis for an entire branch of chemistry.
  • Silicon and Germanium are important semiconductors.
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Nitrogen Family
  • Elements in group 5
  • Nitrogen makes up over  ¾ of the atmosphere.
  • Nitrogen and phosphorus are both important in living things.
  • Most of the world’s nitrogen is not available to living things.
  • The red stuff on the tip of matches is phosphorus.
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Oxygen Family
  • Elements in group 6.
  • Oxygen is necessary for respiration.
  • Many things that stink, contain sulfur (rotten eggs, garlic, skunks, etc.) .
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Halogens
  • Elements in group 7.
  • Very reactive, volatile, diatomic, nonmetals
  • Always found combined with other element in nature .
  • Used as disinfectants and to strengthen teeth.


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The Noble Gases
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The Noble Gases
  • Elements in group 8 (group 0).
  • VERY unreactive, monatomic gases
  • Used in lighted “neon” signs
  • Have a full valence shell.
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Elemental symbol and formula
  • The entry for every element contains a symbol and two numbers.
  • Symbol: One- or two-letter representation for an element.
    • For instance, the symbol for element hydrogen is the letter “H.”
    • Oxygen, O, and sodium, Na, not S.
    • S is the symbol for Sulfur.
    • Symbol for nitrogen is N, but for potassium it’s K, not P.
    • P is the symbol for Phosphorus.
  • The two numbers are atomic number and relative atomic mass.
  • Atomic number represents the number of protons in the nucleus.
  • Relative atomic mass representative how heavy the atom is relative to the mass of hydrogen atom.
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Elemental symbol and formula
  • Formula: one or two letter symbol with a numerical subscript (1 being understood) that represents a single unit of the fundamental particle (one atom or one molecule or a formula unit) that makes up the substance.
  • Two variety of elements:
  • Monatomic: The formula is the same as the symbol, eg. He, Ar, Na.
    • The formula shows that the elementary particles are atomic.
  • Diatomic: Formula contains the subscript 2, eg. H2, O2, N2.
    • Elementary particles are molecules—diatomic molecules.
    • Molecules are particles that are made up of two or more atoms combined (bonded) together.
    • Only the following elements in the periodic table are diatomic elements: Hydrogen, Nitrogen, Oxygen, Fluorine, Chlorine, Bromine and Iodine.
    • The rest are monatomic.
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Diatomic Elements
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Formula and Chemical symbol for some compounds
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Classification
  • An element according to its physical properties, is classified as being a Metal, metalloid or a non-metal
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Practice Questions
  • 1. J04/2/5. Look at the list of five elements below.
  • argon bromine chlorine iodine potassium
    • (a) Put these five elements in order of increasing proton number. [1]


    • (b) Put these five elements in order of increasing relative atomic mass. [1]


    • (d) Which of the five elements in the list are in the same group of the Periodic Table? [1]


    • (e) (i) From the list, choose one element which has one electron in its outer shell. [1]


    • (ii) From the list, choose one element which has a full outer shell of electrons. [1]
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Practice Questions
  • 2. J00/2/1. The diagram shows part of the Periodic Table.
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Practice Questions
    • (ii) Write down the symbol for an element with a smaller proton (atomic) number than lithium, Li.


    • (iv) Write down the symbol for an element which contains atoms with a full outer shell of electrons. [3]
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Practice Questions
  • 3. (b) The diagram shows the atomic structure of an atom of lithium.
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Practice Questions
    • (c) The diagrams show the electronic arrangement of the atoms of two elements.
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Practice Questions
    • (ii) Why are these two elements in the same group of the Periodic Table? [1]

  • 4. The diagram shows an outline of the periodic table.
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Practice Questions
  • Choose your answers only from the letters shown on this outline table.
  • Which letter, A to H, represents an element which:
    • (a) is in Group 3, Letter ............................ [1]
    • (b) is in Period 2, Letter ............................ [1]